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Sulfate and Hydrogen Sulfide in Water

Sulfates and Hydrogen Sulfide

Sulfates are a combination of sulfur and oxygen (SO4, SO3) and are a part of naturally occurring minerals in some soil and rock formations that contain groundwater. The mineral dissolves over time and is released into groundwater.

Sulfur-reducing bacteria, which use sulfur as a food source, are the primary producers of large quantities of hydrogen sulfide (H2S). These bacteria chemically change natural sulfates (SO4) in water to hydrogen sulfide. Sulfur-reducing bacteria live in oxygen-deficient environments such as deep wells, plumbing systems, water softeners and water heaters. These bacteria strip the O2 molecule from the sulfate ion to leave (S) which combines with Hydrogen in water to form H2S.  These bacteria usually flourish in large recirculating water tanks and ponds.

Hydrogen sulfide gas also occurs naturally in some groundwater. It is formed from decomposing underground deposits of organic matter such as decaying plant material. It is found in deep or shallow wells and also can enter surface water through springs, although it quickly escapes to the atmosphere. Hydrogen sulfide often is present in wells drilled in shale or sandstone, or near coal or peat deposits or oil fields.

Ozone is a powerful oxidizer that can destroy the sulfur reducing bacteria, this will reduce odors emanating from your water and improve water quality.  Air Stripping is another common method used to remove H2S odors from water.  See our air-stripping injection systems.

Indications of Sulfate and Hydrogen Sulfide

Sulfate

Sulfate minerals can cause scale buildup in water pipes similar to other minerals and may be associated with a bitter taste in water that can have a laxative effect on humans and young livestock.  Sulfur-oxidizing bacteria produce effects similar to those of iron bacteria. They convert sulfide into sulfate, producing a dark slime that can clog plumbing and/or stain clothing. Blackening of water or dark slime coating the inside of toilet tanks may indicate a sulfur-oxidizing bacteria problem. Sulfur-oxidizing bacteria are less common than sulfur-reducing bacteria.

Hydrogen Sulfide

Hydrogen sulfide gas produces an offensive "rotten egg" or "sulfur water" odor and taste in the water. In some cases, the odor may be noticeable only when the water is initially turned on or when hot water is run. Heat forces the gas into the air which may cause the odor to be especially offensive in a shower. Occasionally, a hot water heater is a source of hydrogen sulfide odor. The magnesium corrosion control rod present in many hot water heaters can chemically reduce naturally occurring sulfates to hydrogen sulfide.

A nuisance associated with hydrogen sulfide includes its corrosiveness to metals such as iron, steel, copper and brass. It can tarnish silverware and discolor copper and brass utensils. Hydrogen sulfide also can cause yellow or black stains on kitchen and bathroom fixtures. Coffee, tea and other beverages made with water containing hydrogen sulfide may be discolored and the appearance and taste of cooked foods can be affected.

High concentrations of dissolved hydrogen sulfide also can foul the resin bed of an ion exchange water softener. When a hydrogen sulfide odor occurs in treated water (softened or filtered) and no hydrogen sulfide is detected in the non-treated water, it usually indicates the presence of some form of sulfate-reducing bacteria in the system. Water softeners provide a convenient environment for these bacteria to grow. A "salt-loving" bacteria, that uses sulfates as an energy source, may produce a black slime inside water softeners.

Potential Health Effects

Sulfate

Sulfate may have a laxative effect that can lead to dehydration and is of special concern for infants. With time, people and young livestock will become acclimated to the sulfate and the symptoms disappear. Sulfur-oxidizing bacteria pose no known human health risk.  The Maximum contaminate level is 250 mg/L.

Hydrogen Sulfide

Hydrogen sulfide is flammable and poisonous. Usually it is not a health risk at concentrations present in household water, except in very high concentrations. While such concentrations are rare, hydrogen sulfide's presence in drinking water when released in confined areas has been known to cause nausea, illness and, in extreme cases, death.

 
Theoretical Amounts of Various Agents Required to Oxidize 1mg/L of Sulfide Ion
 

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